You are correct that this an application of the Doppler Effect. Since the speed of the object is close to the speed of light, we have to include special relativity. Furthermore, since the object is moving directly away from the source, we have the Longitudinal Relativistic Doppler Effect. The equation is as follows (from the ever helpful wikipedia).
Source Frequency / Receiver Frequency = sqrt( (1 + β) / (1 - β ) )
where β = Relative speed between the objects / speed of light, which is 0.7 in this case
The source is the planet, and the receiver is the astronaut. Solving for the receiver frequency, we have:
Receiver Frequency = sqrt( (1 - β) / (1 + β ) ) • Source Frequency
Since the objects are moving apart from each other, the frequency shift has to be less that one. This means that our β will take on a positive value in the above equation.
sqrt( (1 - 0.7) / (1 + 0.7) ) = sqrt ( 0.3 / 1.7 ) = 0.42
Receiver Frequency = 0.42 • Source Frequency:
Therefore,
Receiver Hum Frequency = 0.42 • 220 Hz = 92.4 Hz
Receiver Broadcast Frequency = 0.42 •600 kHz = 252 kHz