Hello, Maddie,
The heat of vaporization is given in kJ/mole. Once we convert 90.8 grams of ethanol to moles ethanol, we can multiply by the heat of vaaporization to find the heat necessary to vaporize the ethanol. Since the question dioes not say that a temperature change occured, we'll assume that the ethanol is already at it's boiling point, and the resulting gas stays at the same temperature (otherwise, we'd need to calculate the heats involved with temperature changes).
Ethanol, C2H5OH, is 46.07 grams/mole. We have 90.8 grams/(46.07 grams/mole) = 1.97 moles C2H5OH
(1.97 moles C2H5OH)*(39.3 kJ/(mole C2H5OH)) = 77.45 kJ (44.5 kJ with 3 sig figs)
Bob