Stan F. answered 03/18/19
Ph.D. Food Science with biology and biochemistry emphasis
The outer membrane is a phospholipid bilayer. It is selectively permeable to small, nonpolar ions such as CO2, O2, It is not permeable to hydrogen ions and serves a second outer barrier together with the inner membrane to form the intermembrane space. Like all membranes it has protein channels for transport of larger and polar molecules. It also serves to protect the inside of the organelle from the cytoplasmic contents. It also contains proteins for recognition (to avoid attack by the immune system.) And remember mitiochondria were once bacteria (endosymbiotic theory.) Bacteria have two "membranes" or cell membrane and cell wall.