Question A can be answered by the following analysis.
die 1 a 3, die 2 a 6
die 1 a 6, die 2 a 3
die 1 a 4, die 2 a 5
die 1 a 5, die 2 a 4
so, there are 4 ways to roll a 9. Since there 36 possible combinations, the chance of rolling a total of 9 on a single roll is 4 divided by 36 = 0.11 or 11%.
Question B cannot be calculated, as pay off is somewhat arbitrary. Currently, Las Vegas casinos pay 1 to 1 on such a bet. That pay off has been the case for a long time.