JACQUES D. answered 08/20/22
Ivy league and MIT educated Chemical Engineer with career as teacher
1) The last significant digit is uncertain. That is what it is indicating.
2) Nonzero digits are always significant. 3.2 units is rounded to the nearest .1 units.
4) Measuring to the nearest .1 ml you must write the measurement of 10 as 10.0 ml to tell people that you measured 10.0 rather than 10.1 or 9.9. If you write 10 ml, that actually implies one sig fig, so it indicates 10, not 20 or 0 ml.