J.R. S. answered 06/30/22
Ph.D. in Biochemistry--University Professor--Chemistry Tutor
∆T = imK is the formula to use for this problem.
∆T = change in boiling point = ?
i = van't Hoff factor for glycerol = 1 since it is a non electrolye
m = molality = mols glycerol / kg water = 14.33 g x 1 mol/92.1 g = 0.156 mol / 0.051 kg = 3.06 m
(this assumes a density for water of 1 g / ml. molar mass glycerol = 92.1 g / mol)
K = boiling point constant for water = 0.512ºC/m
Solving for ∆T we have...
∆T = (1)(3.06 m)(0.512ºC/m)
∆T = 1.57ºC ... this is the CHANGE in the boiling point of water, so the boiling point of the solution is ...
Boiling point = 100º + 1.57 = 101.57ºC (not adjusted for sig. figs.)