the underlying chemical formula for this reaction is
C6H12O6(s) + 6O2(g) → 6CO2(g) + 6H2O(l), meaning that for every 1 mole of glucose that reacts, 6 moles of carbon dioxide are produced
so the calculation you want to do here is
0.450 mol C6H12O6 x (6 mol CO2 / 1 mol C6H12O6) = 2.7 mol CO2
so 2.7 moles of CO2 are produced