
Francisco P. answered 10/17/14
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Rigorous Physics Tutoring
If you evaluate the expression for π/4 you will get 0/0 which is indeterminant.
You could use L'Hopital's rule by taking the derivatives of the numerator and the denominator and retaking the limit.
lim -sin(θ)/1 = -1/√2
θ→π/4