Inactive Tutor answered 10/17/14
Tutor
New to Wyzant
If you evaluate the expression for π/4 you will get 0/0 which is indeterminant.
You could use L'Hopital's rule by taking the derivatives of the numerator and the denominator and retaking the limit.
lim -sin(θ)/1 = -1/√2
θ→π/4