J.R. S. answered 10/19/17
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Ph.D. in Biochemistry--University Professor--Chemistry Tutor
CaSO3 + 2HCl ==> SO2(g) + CaCl2 + H2O
moles CaSO3 used = 3.82 g x 1 mole/120 g = 0.0318 moles
moles SO2 produced = 0.0318 moles CaSO3 x 1 moles SO2/mole CaSO3 = 0.0318 moles SO2
From PV = nRT and solving for V, you have V = nRT/P
V = (0.0318 moles)(62.4 L-torr/K-mole)(317K)/8.27 torr
V = 76.1 liters