Jessica, you only need one equation. Distance = rate x time, right? They'll both have walked the same distance once they meet.
If t = Ray's time, then his sister's time is 10 minutes shorter, or t - 10
Ray's distance is 2t, and his sister's is 6(t - 10) or 6t - 60.
Since the distances are the same, 2t = 6t - 60
-4t = -60
t = 15
So, Ray walks for 15 minutes before his sister, walking for 5 minutes, catches up.
Hope this helps!