Yes, a guy can get either of mother's X chromosome, unless:
1. there is a mutation in one of the X-chromosome that makes that particular X-chromosome carrying ovum incapable of fertilization or arrests the development.
2. there is an haploinsufficient region that arrests development.
3. there is a lethal mutation in one of the X-chromosome that does not support the survival of that particular X-chromosome carrying zygote/embryo/fetus in single dose.
Hope this helps as well.