Great question! With my students, I always check to be sure they know one rule: that variables can only be added to/subtracted from the same variable. I often use the idea of apples and oranges to show this idea. You can only add apples to apples and oranges to oranges. So if they can correctly identify the variables and non-variable pieces of the equation, it's the best way to start.
For simple equations where everything is already on one side of the equal sign, I tell them to put the like terms next to each other. (rearrange the equation).
Such that
3x + 2 + 5x - 4
Becomes
3x + 5x + 2 - 4
Now, I will have them combine the like terms
8x - 2
Sometimes, students will get confused by the negative signs within an equation. So I will rewrite subtraction as plus a negative. This may depend on the equation itself. Sometimes brackets are also a good way to help keep everything together that should be.
Like if
3x - 2 - 5x + 4
3x + (-5x) +(-2) + 4
[3x + (-5x)] + [(-2 +4)]
[3 - 5]x + [-2 + 4]
5 - 3 = 2 so, 3 - 5 = -2
4 - 2 = 2 so, -2 + 4 = 2
Thus,
-2x - 2