a) x = tan(X) and y = tan(Y)
tan(X+Y) = (tanX + tanY)/(1-tanXtanY)
Take the inverse tan of both sides and substitute x and y into right-hand side
X+Y = tan-1((x+y)/(1-xy))
b) Just plug in. x=1/2 and y=1/3 in to the right-hand-side expression and you get tan-1(1) = pi/4
c) Google or look up Maclaurin series for tan-1x. Plug in the value of the first four terms tan-1(x) and tan-1(y) with x = 1/2, y = 1/3, add them and multiiply by 4 to get an approximation for pi.
pi = 4(tan-1(1/2) + tan-1(1/3))
Please consider a tutor. Take care.