To find the relative frequency, first total each column (for singles and couples). Then divide the individual frequency by the total for the group.
For example, for the single group we have
Amount. Frequency. Relative Frequency
51-100 4. 4/58 = 0.069
101-150 11 11/58= 0.190
151-200. 14 14/58=0.241
201-250. 14 14/58=0.241
251-300 11 11/58= 0.190
301-350 4 4/58 = 0.069
Total 58 1.000
Notice the sum of the relative frequency will be 1.000.
Do this for the couples group.