
Sam B. answered 11/28/19
PhD Organic Chemist with years of experience helping students
This is essentially a problem of balancing chemical equations. The first thing to remember in any combustion reaction is that the reaction involves the reaction of an organic compound with O2. So the first thing we write on the left side of the equation is C2H6 + O2. In a combustion reaction the organic compound undergoes an oxidation, and will form the most oxidized carbon species, i.e. CO2. In addition, O2 undergoes reduction to form water. So the overall reaction (eq 1) is:
AC2H6 + BO2 ------> CH2O + DCO2 (1)
2O 3O
2C 1C
6H 2H
In this equation we can tally up the atoms on the left side of the reaction, and do the same for the right. We see that the equation is not balanced. Therefore, we must modify the coefficients A,B,C, and D in such a way to honor the law of conservation of mass. A good place (but not the only place) to start is to look at the carbon count for each side of the equation. We can see that a molecule containing 2 carbons on the left side (C2H6) is tranformed to a molecule containing 1 carbon on the right (CO2). Therefore, we can replace D in the equation with 2A (eq 2).
AC2H6 + BO2 ------> CH2O + 2ACO2 (2)
Next, substitute an actual number for A (it doesn't matter what number, but simpler is better in all cases) Therefore, let's input A = 1. Our new equation is thus eq 3.
C2H6 + BO2 ------> CH2O + 2CO2 (3)
Because we have already assigned the left side of the equation to give 6 H atoms, we must assign C = 1 (eq 4).
C2H6 + BO2 ------> 3H2O + 2CO2 (4)
2C 2C
6H 6H
2B O 7O
With this assignment, we can tally the atom count on both sides and infer that 2B = 7, and thus B = 3.5. Then input this number into the equation.
C2H6 + 3.5O2 ------> 3H2O + 2CO2 (5)
Conventionally, we only use whole numbers for coefficients when balancing equations. So, the last step is to simply multiply the entire equation by the smallest whole number that gives whole numbers for each coefficient in these case we multiply each coefficient by 2. Our final balanced equation is therefore eq 6.
2C2H6 + 7O2 ------> 6H2O + 4CO2 (6)