Distance = (Rate)(Time)
Let x = number of hours driven by car 1 when the second car catches up
Then x - 1 = number of hours driven by car 2
The second car catches up to the first when the distances are the same
So, 72x = 90(x-1)
72x = 90x - 90
18x = 90
x = 5 hours
The second car catches up to the first 4 hours after starting, or 5 hours after the first car departs.