You are half way there!
You have sec(x) = -2 .
cos(x) = 1/sec(x)
So sec(x) = -2 the same place cos(x) = -1/2
cos(x) = -1/2 => cos-1(x) = -1/2
cos(x) is negative in the second and third quadrant . So using a reference angle of 60 (since cos (1/2) = 60º)
In the second and third quadrant you get 180º- 60º = 120º and 180º+ 60º = 240º ( You can also use your unit circle to easily find these values!)
So cos-1(-1/2 ) = sec-1(2) = 120º and 240º or 2π/3 and 4π/3
(To convert from degrees to radians multiply by π/180)