Too close to home here. Use these SOE to solve for the percentage of each mixture. Then go from there.
x+y=1
1x+4y=2
y=1-x
x+4(1-x)=2
x+4-4x=2
-3x=-2
x=2/3
y=1/3
Therefore x(1% solution) = 100ml is 2/3rds of the solution. Y (4% solution) is 1/3rd of the solution or 50 ml.
Check:
.666(1)+.333(4)=2