
Maya P. answered 12/18/22
Geoscientist to help you in Earth and Environmental Science!
The atmosphere is a rapidly mixed (and well mixed) reservoir. While some cities and other centers of high emissions can cause higher relative concentrations of carbon dioxide at Earth's surface, carbon dioxide in the atmosphere as a whole is what causes global warming (the augmentation of the greenhouse effect and rapid homogenous warming of Earth's surface). We see the influence of seasons in the long-term record of carbon dioxide concentration at the HI station: the N. hemisphere has more plant growth so there's a lower concentration in summer and higher concentration in winter. Additionally, winds and climate modes can change relative concentrations of carbon dioxide in the atmosphere, including the stratosphere. These also affect how various ocean mixed layers take up carbon dioxide (surface). So, yes, you can have variability in surface concentration on several scales, but global warming concerns global scales, as the name suggests, which will look at the total concentration in every reservoir as well as the average trends. Scale is an important part of answering many climate questions and I'm happy to discuss this more if you'd like.
Here are some papers you may find useful for your inquiry:
Jiang and Yung (2019)
Prather (2022)
Kurbatova (2020) - to look at variability in concentration around a Vietnamese forest
Coutts, Beringer, and Tapper (2007) - study around urban concentrations in AUS
Gao et al. (2018) - probably the most interesting to you as it's looking at an urban to rural transect
The continuation of Keeling's work (HI monitoring): https://gml.noaa.gov/ccgg/trends/