J.R. S. answered 08/27/18
Tutor
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Ph.D. in Biochemistry with an emphasis in Neurochemistry/Neuropharm
If you know how to make the buffer, and it sounds like you do, then you just use that buffer as the solvent to dissolve the solute NaCl.
Is the final solution supposed to be pH 7 or 7.1? In your question you state the buffer is pH 7, but then state the two solutions in the beaker should be pH 7.1. This doesn't make sense. I'll assume you want the pH to be 7.
To make 1 M NaCl, you need 58.44 g NaCl/Liter of solution.
To make 10 mls, you need 58.44 g/L x 0.01 L = 0.5844 g NaCl
So, you would weigh out 0.58 g NaCl and dissolve in enough 0.02 M sodium phosphate buffer to make a final volume of 10 mls. Then use 0.75 ml of this solution. The pH should be the same as the pH of the original buffer since NaCl is a neutral salt.

J.R. S.
tutor
The NaCl will affect the [Na+] of the buffer, but not the acid/conjugate base concentrations. What you read about making the stock solutions of mono and di sodium phosphates containing 1 M NaCl would be another way to do it, but I see no obvious advantage. Which ever way is easiest for you to do. Whenever I've made this (and I've made it many, many times), I've done it the way I outlined. I would have the stock phosphate buffer on hand, and would just use it to dissolve whatever solute I needed.
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08/27/18
Adam C.
08/27/18