J.R. S. answered 07/20/17
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Sodium hydrogen carbonate is NaHCO3, also known as sodium bicarbonate.
0.5 M means 0.5 moles/liter
To make 50 ml, that is equivalent to 0.050 liters, so you will need 0.5 moles/L x 0.05 L = 0.025 moles NaHCO3
Molar mass NaHCO3 = 84.0 g/mole
Thus to make 50 ml (0.050 L) of 0.5 M NaHCO3 you need 0.025 moles x 84.0 g/mole = 2.1 grams
Weigh out 2.1 grams NaHCO3 and dissolve in enough water to make a final volume of 50 ml.