the balanced chemical equation that we're starting with here is
CuCO3 ⋅ Cu(OH)2 → CO2 + H2O + 2CuO
meaning that the mole ratio is 1 mole CuCO3: 2 moles of CuO
next then i would determine the moles of CuCO3 by dividing the given mass by the molar mass
Moles = 1.01 g / 221.114 g/mol = 0.004568 mol CuCO3
using the mole ratio that becomes
Moles of CuO = 0.004568 mol CuCO3 x 2 mol CuO / 1 mol CuCO3 = 0.009136 mol CuO
the last step then is multiplying that value by the molar mass
0.009136 mol CuO x 79.545 g/mol = 0.727 g
meaning that you end up producing approximately 0.727 grams of CuO for the theoretical yield in this scenario