The average rate of change of volume is (V(t2)-V(t1))/(t2-t1)
V = (4/3) πr3 = (4/3)π(3t)3 = 36πt3
Now just plug into the formulas with t2=4 and t1=1
Please consider a tutor. Take care.
You could have calculated the integral from 1 to 4 of (dV/dt) dt divided by (4-1), but there is no need to derive dV/dt from related rates as the integral is V(t).