The definition of independence of two random events A and B is
P(A∩B) = P(A)P(B)
In our case
P(X1 = 0 ∩ X2 = 0) = P(X1 = 0)P(X2 = 0)
P(X1 = 0 ∩ X2 = 1) = P(X1 = 0)P(X2 = 1)
P(X1 = 1 ∩ X2 = 0) = P(X1 = 1)P(X2 = 0)
P(X1 = 1 ∩ X2 = 1) = P(X1 = 1)P(X2 = 1)
We are given that P(Xj = 0) = P(Xj = 1) = 0.5
So the right hand sides of all four equations are 0.25.
(i)
The information about "no mechanism ..." is probably meant to imply that
all the four possibilities on the left of our equations are equally likely,
which would given them the probability of 0.25.
(ii)
P(X1 = 0 ∩ X2 = 0) = 0 ≠ P(X1 = 0)P(X2 = 0)
Therefore X1 and X2 are not independent.