J.R. S. answered 12/13/21
Ph.D. University Professor with 10+ years Tutoring Experience
An easy way to determine the limiting reactant is to divide the moles of each reactant by the corresponding coefficient in the balanced equation. Whichever value is less will be the limiting reactant.
4 Au(s) + 8 NaCN (aq) + O2(g) + 2 H2O(l) → 4 NaAu(CN)2(aq) + 4 NaOH(aq)
For Au: 86.7 g x 1 mol / 197 g = 0.440 mol (÷4=0.11)
For NaCN: 0.75 L x 1.8 mol/L = 1.35 mol (÷8=0.17)
Limiting reactant is Au since 0.11 < 0.17