J.R. S. answered 04/14/21
Ph.D. University Professor with 10+ years Tutoring Experience
Liquid ammonia, possesses strong ionizing powers, so the NH4Cl will dissociate into NH4+ and Cl-. Obviously, NH4+ is a Bronsted-Lowry acid as it will donate a proton. This would explain the acidic nature of the solution. Not sure about the equation you present, but seems like the equilibrium would be between NH4+ and NH3