
Ryan L. answered 12/15/20
Current Dental Student Tutoring Chemistry
Since this type of orbital hybridization is commonly used in organic chemistry with regards to carbon my answers to the questions below will be assuming the "atom" in your question is carbon.
The maximum number of σ bonds that the atom can form is 4
The maximum number of p-p bonds that the atom can form is 0
σ bonds are the initial bond between any two atoms. For example in the molecule CH4 the carbon has a single bond (AKA σ bond) to each of the hydrogens and in this case carbon is sp3 hybridized. Since carbon can only form 4 bonds there are no empty p orbitals available for a bond.
bonds can be thought of as the double or triple bonds in a chemical structure. For example in the molecule C2H4 each carbon is sp2 hybridized and therefore each has 1 empty p orbital available for bonding in addition to the sp2 orbital on each carbon atom that interact to form the σ bond. In line with our analysis C2H4 has a double bond between the 2 carbon molecules. Hope this helps!