J.R. S. answered 09/21/20
Ph.D. University Professor with 10+ years Tutoring Experience
2NaNO3 ===> 2NaNO2 + O2 ... balanced equation
Each mole of NaNO3 produces 1 mole of NaNO2 (1:1 mole ratio)
moles of NaNO2 produced = 0.2500 g x 1 mol NaNO2/69 g = 0.003623 moles
moles NaNO3 present = 0.003623 moles NaNO3
mass NaNO3 = 0.003623 mol x 84.99 g/mol = 0.3079 g NaNO3
% NaNO3 = 0.3079 g/0.4230 g (x100%) = 72.80%