Let L = the length
Let W = the width
We know that the length is 3 less than twice its width, or
L = 2W - 3
The perimeter of a rectangle is equal to the sum of its sides. A rectangle has 4 sides, with 2 length and 2 width
Perimeter = 2L + 2W
Substitute in your equation for L to get
Perimeter = 2(2W - 3) + 2W
= (4W - 6) + 2W
= 6W - 6
Perimeter = 6W - 6 where W is equal to the width of the rectangle