Rolling an even number or a multiple of 5 on a six sided dice.
You can't have an even number that is a multiple of 5. For example, 2, 4, and 6. 5 is the only number that can have a multiple of 5.
P(even number or multiple of 5) = P(even number) + P(multiple of 5) = (3/6) + (1/6) = 2/3 = 0.667