4.6 liters of mix will contain 2.99 liters AF and 1.61 liters W (AF = Antifreeze & W = Water)
To get a 50% mix of antifreeze, you must have 2.3 liters AF & 2.3 liters W in the final mix.
So you must drain .69 liters of AF and therefore .3715 liters of W or 1.06154 liters of 65% antifreeze mix
Then you will have 2.3 liters of AF and 1.2385 liters W = 3.5385 liters total mix in the radiator
So, then add 1.06154 liters of W to get to now have 2.3 liters of W & 2.3 liters of AF for a 50% mix !