Let's assume the house is 1000 ft2 (This is an arbitrary number, any reasonable will be OK)
Then, Mr. Sunday takes 4 hours to paint 1000 ft2 or he can paint 1000 ft2/4 hours or 250 ft2/hour
Then, Mr. Armstrong takes 5 hours to paint 1000 ft2 or he can paint 1000ft2/5 hours = 200 ft2/hour
So, both working together they can paint 450 ft2/hour, So, 1000 ft2/(450 ft2/hour) = 2.22 hours
So, working together, it takes them about 2 hours and 13 minutes!