Start by calculating how many standard deviations away from the mean your number is. This is your Z score.
Z = (690-700.5)/20 = -.525
Now we have a possible source of error. Z scores in Z tables only go to 2 decimal places. Which might be .52 or .53 in this case. Looking up .52 and .53 in a Z table, You would get .6985 or .7019. If you plug in your number to a calculator, you get that .700208 number, which is probably more accurate.