In the first case, n, your sample size is 306, and p, your chance of success, is .657
In the second case, n = 100 and p = .700.
Your standard error for this sort of situation is sqrt(p*f/n), where p = chance of success, f = chance of failure, and n = sample size.
1st case: s.e. = .0271
2nd case: s.e. = .0458
In both cases, your 95% confidence interval is going to be +/- 1.96 standard errors from your mean.
1st case: (0.647,0.753)
2nd case: (0.567,0.747)