Dr. Pamela H. answered 03/14/19
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After an electron has been removed from an atom, the effective nuclear charge (the positive nuclear charge that an electron actually feels coming from the nucleus) increases because the number of protons in the nucleus remains the same, whereas the number of electrons balancing that nuclear charge is decreasing due to loss of an electron. Also, the next electron to be removed may be a little closer to the nucleus, making the effective nuclear charge that it feels higher than the effective nuclear charge felt by the first electron that was removed.