Distance = Speed*Time, and Time = Distance/Speed. When the second car reaches point A, the first car has traveled (60 kph*0.25 hours) = 15 km
A - The second car is going 20 kph faster; it can close the 15 km gap in 15 km/20 kph = 0.75 hours.
B - In 0.75 hours, the second car will travel 80 kph*0.75 hours = 60 km