Let S = price of scones and C = price of coffee.
Luis: 7S + 4C = 26.28
Rachel: 6S + 5C = 25.37
There is NO EASY way to solve this set, i.e. any solution is messy.
The least nuisance is to use determinants which you may not know about.
Next, I would advise: multiply the first equation by 5 and the second by 4.
Then subtract to eliminate the C.
Solve for S and use that value to get C.