J.R. S. answered 10/19/17
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Na2S would form a black precipitate with Pb(NO3)2. The others will also form a precipitate with Pb(NO3)2, but PbS (lead sulfide) is the one that is black.
Na2S(aq) + Pb(NO3)2 (aq) ===> 2NaNO3(aq) + PbS(s)