Two vectors u and v whose dot product is zero are orthogonal.
and the dot product is x1*x2 + y1*y2 + z1*z2
Let's check u and v from your problem.
u*v = 2*3 + 0*1 - 3*2 = 0. So this vectors are orthogonal.
Let's check u and w
u*w = 2*0 + 0*(-2) + (-3)*1 = -3
Not orthigonal
Now we need to find an angle between those vectors.
u*w = |u|*|w|*cos(∠uw)
so as we know |u| = √(x2+y2+z2) = √(4+0+9) = √13
Could you find |w| and find the cosine of the angle from this information? Or do you need more help?
I also didn't check if v and w are orthogonal. Could you do that?
As for (c) part, you could take x of u, y of v and z of w. And you get
2x+3y+0z=1
0x+1y-2z =5
and what would be the 3rd equation here?
Could you solve the system now?