This is an initial value problem (IVP). You found the eigenvalues and corresponding eigenvectors, so you know the general solution is
x(t) = c1[1,3]e2t + c2[1,1]e4t
To fix the two constants c1 and c2, you need to impose the initial condition, x(0)=[2,-1].
You get
x(0)=[2,-1]=c1[1,3] + c2[1,1]
This you can write as a system of 2 equations:
2=c1+c2
-1=3c1+c2
You could solve this by putting it into matrix form again, but it's just as easy to solve it "by hand": subtract the second from the first equation and get
3=-2c1, so that c1=-3/2, which then implies c2=7/2.
So the solution to the IVP is
x(t) = -3/2[1,3]e2t + 7/2[1,1]e4t