J.R. S. answered 04/10/24
Ph.D. University Professor with 10+ years Tutoring Experience
Molar mass carbon dioxide (CO2) = 44.0 g / mole
8.47 g CO2 x 1 mol / 44.0 g = 0.1925 moles CO2
At STP, 1 mole of any ideal gas occupies 22.4 liters, thus
@STP: 0.1925 mols CO2 x 22.4 L / 1 mol = 4.31 L
At 140ºC and 5.00 atm, we will use the ideal gas law:
PV = nRT and V = nRT/P
V = (0.1925 mol)(0.0821 Latm/Kmol)(413K) / 5.00 atm
V = 1.31 L
At 239K and 109 laps(?) .. never heard of laps units, so will assume you meant kPa (kilopascals)
109 kPa x 1 atm / 101.325 kPa = 1.076 atm
PV = nRT and V = nRT/P
V = (0.1925 mol)(0.0821 Latm/Kmol)(239K) / 1.076 atm
V = 3.51 L