
Kim W.
asked 09/12/23General chemistry freezing point
Camphor boils at 207.4 Celsius. What mass of ethanol (46.07g/mol) dissolved in 675.0 g of camphor will raise the boiling point to 211.6 Celsius?
Formula: delta Tb = Kb(constant boiling point elevation) x i( vant Hoff constant) x m( molality)
notes: The Kf wasn’t given to me and I know that I need to find the molality to help assist me to find the mass of ethanol that’s needed to raise the boiling point)
1 Expert Answer
J.R. S. answered 09/13/23
Ph.D. University Professor with 10+ years Tutoring Experience
Kb for camphor = 5.95
∆T = imKb
∆T = 211.6 - 207.4 = 4.2º
i = van't Hoff factor =1 for ethanol, a non electrolyte
m = molality = moles ethanol/kg camphor = ?
Kb = 5.95
Solving for m ...
m = ∆T / (i)(K) = 4.2 / (1)(5.95)
m = 0.706 mols / kg
Since there are 675.0 g of camphor, that is = 0.675 kg of camphor
moles ethanol = 0.706 mols / kg x 0.675 kg = 0.476 mols ethanol
Mass of ethanol = 0.476 mols x 46.07 g / mol = 21.95 g ethanol
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J.R. S.
09/12/23