A ratio of 4:5 means you could think of the angles as 4x and 5x and you can use Algebra to determine what the "x" is.
Since the angles in a quadrilateral add to 360° then:
85 + 230 + 4x + 5x = 360
315 + 9x = 360
9x = 45
x = 5
So, one angle is 4•5 or 20°
And the other angle is 5•5 or 25°