J.R. S. answered 02/26/23
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Ca2+and Cl- are isoelectronic with Ar.
Ar has the electron configuration of [Ne]3s23p6
S = [Ne]3s23p4; S2+ = [Ne]3s23p2
Ca = [Ar]4s2; Ca2+ = [Ar]
Cl = [Ne]3s23p5; Cl- = [Ar]
Na = [Ne]3s1; Na+ = [Ne]