J.R. S. answered 12/28/22
Ph.D. University Professor with 10+ years Tutoring Experience
2C2H6(l) + 7O2(g) ==> 4CO2(g) + 6H2O(l) .. balanced equation
At STP, we can use liters in place of moles in interpreting the balanced equation. Thus, we can read this as
"2 liters of C2H6 reacts with 7 liters of O2 to produce 4 liters of CO2".
Now, using this stoichiometry, we can solve the problem:
52.53 L O2 x 4 L CO2 / 7 L O2 = 30.02 L CO2
If you don't trust this approach, do it the long way using the ideal gas law:
PV = nRT
P = 1 atm (STP)
V = 52.53 L
n = moles of O2 = ?
R = gas constant = 0.0821 Latm/Kmol
T = 273K (STP)
n = PV/RT = (1)(52.53) / (0.0821)(273)
n = 2.34 mols O2
Now use the stoichiometry of the balanced equation to find moles of CO2 produced:
2.34 mol O2 x 4 mols CO2 / 7 mols O2 = 1.34 mols CO2 produced
Convert this to volume of CO2:
V = nRT / P = (1.34 mol)(0.0821)(273) / 1
V = 30.03 L CO2