J.R. S. answered 07/01/22
Ph.D. University Professor with 10+ years Tutoring Experience
According to the law of conservation of mass, the mass of the starting material must be the same / equal to the mass of the final products. Thus, if you begin with 20.5 g of reactants (NH4Cl), the sum of the mass of the products must also be 20.5 g. Since one of the products has a mass of 9.4 g, the other must make up the difference.
NH4Cl ==> NH3 + HCl
20.5 g........9.4 g.....x g
Thus, you have 20.5 g - 9.4 g = 11.1 g = mass of HCl