Assuming ppm is parts per million by mass: 1ppm Cu2+ is the same as 10-6 g Cu2+/g W (dilute assumed)
or, for this problem, find g Cu2+/ g Water and multiply by 106 to get ppm
First you have to figure out the mg of Cu2+ ions:
mass of Cu(NO3)3 * molar mass of Cu/molar mass of Cu(NO3)2 = 232.29 mg *(63.55/187.56) = 78.706 mg Cu2+
You can take the ratio of masses and and covert it to g/g:
78.706 mg Cu2+/1.45 kg W * 1 g/1000mg * 1 kg/ g = 54.28 x 10-6 g Cu2+/g W
Now multiply by 106 and you get 54.28 ppm. Note that if you just took the ratio of mg of solute to kg of water, that is already in ppm because mg are 10-6 kg - something you can use in the future.
Please consider a tutor. take care.