J.R. S. answered 06/21/22
Ph.D. University Professor with 10+ years Tutoring Experience
For this type of problem, it's probably best to use an ICE table.
Since the volume is 2 L, we can calculate the concentrations as
[H2] = 1.50 mol / 2 L = 0.75 M
[I2] = 3.00 mol / 2 L = 1.50 M
H2 (g) + I2 (g) ↔ 2 HI (g)
0.75.........1.50............0...........Initial
-x............-x................+2x........Change
0.75-x....1.50-x...........2x..........Equilibrium
Kc = 25.0 = [HI]2 / [H2][I2]
25.0 = (2x)2 / (0.75-x)(1.50-x)
25.0 = 4x2 / x2 - 2.25x + 1.125
4x2 = 25x2 - 56.25x + 28.125
21x2 - 56.25x + 28.125 = 0
x = 0.665 (be sure to check the math)
Concentrations at equilibrium are as follows:
[H2] = 0.75 - 0.665 = 0.085 M
[I2] = 1.50 - 0.665 = 0.835 M
[HI] = 2 x 0.665 = 1.33 M