J.R. S. answered 05/21/22
Ph.D. University Professor with 10+ years Tutoring Experience
First, write the correctly balanced equation for the reaction taking place...
(NH4)2CO3(aq) + 2AgNO3(aq) ==> Ag2CO3(s) + 2NH4NO3(aq) ... balanced equation
Since (NH4)2CO3 is present in excess, the moles of AgNO3 will determine the theoretical yield of Ag2CO3 since it will be the limiting reactant.
moles AgNO3 present = 54.0 ml x 1 L / 1000 ml x 0.667 mol / L = 0.03602 mols AgNO3
Grams of Ag2CO3 formed (use the mol ratio of the balanced equation and molar mass Ag2CO3 to find this value)
0.03602 mols AgNO3 x 1 mol Ag2CO3 / 2 mols AgNO3 x 275.7 g Ag2CO3 / mol = 4.97 g Ag2CO3 (3 s.f.)