J.R. S. answered 05/18/22
Ph.D. University Professor with 10+ years Tutoring Experience
∆E = U = q + w
q = heat = -5.00x102 kJ (negative sign because heat is released from system into surroundings)
w = work = 5.00x102 kcal (positive sign because work is done ON the system)
Now we have to get our units to match. To do so, we will convert 5.00x102 kcal to kJ as follows:
1 kcal = 4.184 kJ
5.00x102 kcal x 4.184 kJ/kcal = 2.09x103 kJ
Finally, solve for ∆E/∆U
∆E/∆U = -500 kJ + 2090 kJ = +1592 kJ